Group III-V Device Structure Having a Selectively Reduced Impurity Concentration

ABSTRACT

There are disclosed herein various implementations of a semiconductor structure and method. The semiconductor structure comprises a substrate, a transition body over the substrate, and a group III-V intermediate body having a bottom surface over the transition body. The semiconductor structure also includes a group III-V device layer over a top surface of the group III-V intermediate body. The group III-V intermediate body has a continuously reduced impurity concentration wherein a higher impurity concentration at the bottom surface is continuously reduced to a lower impurity concentration at the top surface.

The present application claims the benefit of and priority to a pendingprovisional application entitled “impurity Graded III-Nitride MaterialStructures and Methods,” Ser. No. 61/537,540 filed on Sep. 21, 2011. Theentire disclosure in this pending provisional application is herebyincorporated fully by reference into the present application.

BACKGROUND

I. Definitions

As used herein, the phrase “group III-V” refers to a compoundsemiconductor that includes a group V element and at least one group IIIelement. Moreover, the phrase “III-Nitride” or “III-N” refers to acompound semiconductor that includes nitrogen (Ni and at least one groupIII element, including aluminum (Al), gallium (Ga), indium (In), andboron (B), and including but not limited to any of its alloys, such asaluminum gallium nitride (Al_(x)Ga_((1-x))N), indium gallium nitride(In_(y)Ga_((1-y))N), aluminum indium gallium nitride(Al_(x)In_(y)Ga_((1-x-y))N), gallium arsenide phosphide nitride(GaAs_(a)P_(b)N_((1-a-b))), and aluminum indium gallium arsenidephosphide nitride (Al_(x)In_(y)Ga_((1-x-y))AS_(a)P_(b)N_((1-a-b))), forexample. III-Nitride also refers generally to any polarity including butnot limited to Ga-polar, N-polar, semi-polar or non-polar crystalorientations. A III-Nitride material may also include either theWurtzitic, Zincblende, or mixed polytypes, and may includesingle-crystal, monocrystalline, polycrystalline, or amorphousstructures.

II. Background Art

Group III-V semiconductors, such as gallium nitride (GaN) or otherIII-Nitride materials, are used in many microelectronic implementationsin which high power density and high efficiency switching are required.Examples of such implementations include field-effect transistors (FETs)and high electron mobility transistors (HEMTs).

Although the intrinsic material properties of III-Nitride semiconductorsenable fabrication of high performance devices in theory, as a practicalmatter, conventional growth environments for III-Nitride materialstypically include impurity sources. The presence of those impuritysources in the III-Nitride growth environment can cause unintentionaldoping of critical device layers. In HEMTs, for example, as well as inother high speed switching devices, such unintentional impurity dopingmay adversely compromise device performance.

SUMMARY

The present disclosure is directed to a group III-V device structurehaving a selectively reduced impurity concentration, substantially asshown in and/or described in connection with at least one of thefigures, and as set forth more completely in the claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 presents a block structure corresponding to an exemplary groupIII-V device structure having a selectively reduced impurityconcentration, according to one implementation.

FIG. 2 presents a block structure corresponding to an exemplary groupIII-V device structure having a selectively reduced impurityconcentration, according to another implementation.

FIG. 3 presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to one exemplary implementation.

FIG. 4 presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 5A presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 5B presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 5C presents a, graph corresponding to a selectively reducedimpurity concentration across portions of the III-Nitride devicestructure shown by FIG. 2, according to another exemplaryimplementation.

FIG. 5D presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 5E presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 5F presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 5G presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 5H presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 6A presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 6B presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 6C presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 6D presents a graph corresponding to a selectively reduced impurityconcentration across portions of the III-Nitride device structure shownby FIG. 2, according to another exemplary implementation.

FIG. 7A presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 7B presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 7C presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 7D presents a graph corresponding to a selectively reduced impurityconcentration, showing a continuous reduction in impurity concentrationacross portions of the III-Nitride device structure shown by FIG. 2,according to another exemplary implementation.

FIG. 7E presents a graph corresponding to a selectively modifiedimpurity concentration across portions of a transition body of theIII-Nitride device structure shown by FIG. 2, and showing a continuousreduction in impurity concentration across a portion of the III-Nitrideintermediate body of the device structure, according to one exemplaryimplementation.

FIG. 7F presents a graph corresponding to a selectively modifiedimpurity concentration across portions of a transition body of theIII-Nitride device structure shown by FIG. 2, and showing a continuousreduction in impurity concentration across a portion of the III-Nitrideintermediate body of the device structure, according to anotherexemplary implementation.

FIG. 8 presents a diagram relating exemplary critical electric fieldsproduced in a III-Nitride device structure by an applied voltage, andexemplary selective reduced impurity concentrations within theIII-Nitride device structure.

DETAILED DESCRIPTION

The following description contains specific information pertaining toimplementations in the present disclosure. One skilled in the art willrecognize that the present disclosure may be implemented in a mannerdifferent from that specifically discussed herein. The drawings in thepresent application and their accompanying detailed description aredirected to merely exemplary implementations. Unless noted otherwise,like or corresponding elements among the figures may be indicated bylike or corresponding reference numerals. Moreover, the drawings andillustrations in the present application are generally not to scale, andare not intended to correspond to actual relative dimensions.

Group III-V semiconductors include III-Nitride materials formed ofgallium nitride (GaN) and/or its alloys, such as aluminum galliumnitride (AlGaN), indium gallium nitride (InGaN), and aluminum indiumgallium nitride (AlInGaN). These materials are semiconductor compoundsthat have a relatively wide, direct bandgap and strong piezoelectricpolarizations, and can enable high breakdown fields and the creation oftwo-dimensional electron gases (2DEGs). As a result, III-Nitridematerials such as GaN are used in many microelectronic implementationsin which high power density and high efficiency switching are required.Examples of such implementations include field-effect transistors(FETs), high electron mobility transistors (HEMTs), and diodes.

As previously discussed, although the intrinsic material properties ofIII-Nitride semiconductors enable fabrication of high performancedevices in theory, as a practical matter, conventional growthenvironments for III-Nitride materials typically include impuritysources. For example, carbon impurities resulting from metalorganicsources may be introduced into III-Nitride materials grown usingmetalorganic vapor phase epitaxy (MOCVD), also known as organometallicvapor phase epitaxy (OMVPE). The presence of impurity sources in theIII-Nitride growth environment can cause unintentional doping ofcritical device layers.

In transistors such as HEMTs, for example, unintentional impurity dopingmay undesirably result in an increased dynamic Rdson, and other effectsadversely impacting device performance. However, it is noted thatcareful manipulation of the growth conditions used to produceIII-Nitride or other group III-V semiconductor materials can selectivelyreduce the impurity profiles within certain key device regions toenhance or optimize device performance.

The present application discloses semiconductor materials includingIII-Nitride materials and methods of forming these materials so as tohave continuously reduced, or otherwise selectively reduced, impurityconcentrations. For example, by grading or otherwise tailoring theimpurity concentration profiles within a layer or layers of a HEMTdevice structure, the present application enables formation ofelectronic devices which exhibit low leakage, low dynamic Rdson, highpunch-through (lateral breakdown), and high vertical breakdown orstandoff capability.

It is noted that although carbon impurity concentrations arespecifically referenced in the application, different impurity speciesmay be present and may be selectively reduced according to the presentconcepts. For example, carbon (C), oxygen (O), hydrogen (H), silicon(Si), germanium (Ge), magnesium (Mg), beryllium (Be), zinc (Zn), iron(Fe), chromium (Cr), and cadmium (Cd) may be unintentionally present orselectively introduced to specific layers or structures in a III-Nitrideor other group III-V semiconductor structure. Furthermore, while thesespecific impurity materials are described, it will be appreciated thatadditional impurities can be included in a semiconductor structurewithout departing from the scope of the present concepts.

Moreover, it is further noted that impurity concentrations resultingfrom the presence of environmental impurity sources in the growthenvironment during growth of a III-Nitride or other group III-V materialbody can correspond in general to the growth rate and/or growthtemperature of the body during its fabrication. For example, a decreasein impurity concentration of a III-Nitride body may result from adecrease in the growth rate of the III-Nitride body during growth.Conversely, a decrease in impurity concentration of a III-Nitride bodymay result from an increase in the growth temperature of the III-Nitridebody during growth.

FIG. 1 presents a block structure corresponding to an exemplary groupIII-V device structure having a selectively reduced impurityconcentration, according to one implementation. As shown in FIG. 1,semiconductor structure 100 includes transition body 110, group III-Vintermediate body 112 having bottom surface 111 over transition body110, and group III-V device layer 114 over top surface 113 of groupIII-V intermediate body 112. According to the present implementation,group III-V intermediate body 112 may be a doped III-Nitride layer. Insome implementations, group III-V intermediate body 112 may be animpurity doped graded III-Nitride layer having a selectively reducedimpurity concentration wherein a higher impurity concentration at bottomsurface 111 is selectively reduced to a lower impurity concentration attop surface 113. Moreover, in one implementation, it may advantageous ordesirable to fabricate group III-V intermediate body 112 so as to have acontinuously reduced impurity concentration wherein a higher impurityconcentration at bottom surface 111 is continuously reduced to a lowerimpurity concentration at top surface 113.

It is noted that when a layer or body is referred to as being “on”,“over”, or “overlying” another layer, body, or substrate, the layer orbody described as “on”, “over”, or “overlying” can be directly on theunderlying layer, body, or substrate, or an intervening layer or bodymay also be present. A layer described as “directly on” another layer,body, or substrate indicates that no intervening layer or body ispresent. It is further noted that when a layer or body is referred to asbeing “on”, “over”, or “overlying” another layer, body, or substrate,the layer or body described as “on”, “over”, or “overlying” may coverthe entire underlying layer, body, or substrate, or a portion of theunderlying layer, body, or substrate.

Moreover, as used herein, the term “impurity doped graded layer” or“impurity graded layer” refers to a layer having an impurityconcentration profile that varies across at least a portion of thethickness of the layer. Thus, group III-V intermediate body 112 includesat least two different impurity concentrations at different depthswithin the layer. As is described in greater detail below, the impurityconcentrations (e.g., dopant profiles) or grading schemes of group III-Vintermediate body 112 can be varied in a number of ways. Although theselectively reduced impurity concentration may change across group III-Vintermediate body 112 according to any of a variety of impurityconcentration profiles, it may be advantageous for such a profile tohave a higher impurity concentration at bottom surface 111 and a lowerimpurity concentration at top surface 113. It is generally advantageousto tailor the selective reduction of the impurity concentration withingroup III-V intermediate body 112 in a manner that provides sufficientdevice properties including low leakage, low dynamic Rdson, highpunch-through (lateral breakdown) and high vertical breakdown/standoffcapability.

In certain implementations, in addition to group III-V intermediate body112 having a selectively reduced impurity concentration, group III-Vintermediate body 112 may be a compositionally graded III-Nitride body.That is to say, group III-V intermediate body 112 may have a firstIII-Nitride composition at bottom surface 111 and a second III-Nitridecomposition above bottom surface 111, such as between bottom surface 111and top surface 113.

In addition, it is noted that the impurity concentration of group III-Vintermediate body 112 being selectively reduced as disclosed herein maybe produced by more than one impurity species. Under thosecircumstances, one, two, or more of the impurity concentrations may becontinuously or otherwise selectively reduced between bottom surface 111and top surface 113, resulting in a reduced overall impurityconcentration at top surface 113 relative to bottom surface 11.Moreover, the impurity concentrations corresponding respectively to eachimpurity species may be reduced based on similar or dissimilar impurityconcentration profiles.

FIG. 2 presents a block structure corresponding to an exemplary groupIII-V device structure having a selectively reduced impurityconcentration, according to another implementation. As shown in FIG. 2,semiconductor structure 200 includes substrate 202, transition body 210over substrate 202, III-Nitride intermediate body 212 having bottomsurface 211 over transition body 210, and group III-Nitride device layer214 over top surface 213 of group III-V intermediate body 212. Accordingto the present implementation, III-Nitride intermediate body 212 may bean impurity doped graded III-Nitride body having a selectively reducedimpurity concentration, wherein a higher impurity concentration atbottom surface 211 is selectively reduced to a lower impurityconcentration at top surface 213.

Transition body 210, group III-Nitride intermediate body 212, andIII-Nitride device layer 214 correspond in general to transition body110, group III-V intermediate body 112, and group III-V device layer114, respectively, in FIG. 1. Also shown in FIG. 2 are bottom surface209 of transition body 210 and top surface 215 of III-Nitride devicelayer 214. Substrate 202 may be formed of materials such as siliconcarbide (SiC), bulk III-Nitride material, Si, sapphire, or any othersuitable material. Furthermore, substrate 202 may be single crystal,polycrystalline, or a composite substrate.

As used herein, a silicon, or Si, substrate may refer to any substratethat includes a silicon surface. Examples of suitable Si substratesinclude substrates that are composed entirely of Si (e.g., bulk Siwafers), silicon-on-insulator (SOI) substrates, silicon-on-sapphiresubstrates (SOS), and separation by implantation of oxygen (SIMOX)process substrates. Suitable Si substrates can also include compositesubstrates that have a silicon wafer bonded to another material such asdiamond, aluminum nitride (AlN), or other polycrystalline materials.

In some implementations, Si substrates having different crystallographicorientations may be used. In some cases, silicon (111) substrates may beadvantageous. In other cases, silicon (100) or (110) substrates may bepreferred. In certain other implementations, the Si substrate, such assubstrate 202, may have various device layers, homo junctions,heterojunctions or circuit layers embedded in the substrate, or formedon the front-side or back-side of the substrate. Such a siliconsubstrate may be semi-spec standard thickness, or thicker, or in someimplementations thinner than semi-spec standards. In someimplementations, for example, the Si substrate may have a diameter ofless than one hundred millimeters (100 mm), while in otherimplementations, the substrate may have a diameter in a range fromapproximately 100 mm to approximately 150 mm. In yet otherimplementations, the substrate diameter may be in a range fromapproximately 150 mm to approximately 200 mm, or larger. In still otherimplementations, the silicon substrate may include a textured surface ormay have a non-planer surface.

As shown in FIG. 2, transition body 210 is fabricated over substrate202. Transition body 210 may be fabricated as a III-Nitride bodyincluding two or more interlayers as described in U.S. ProvisionalPatent Application No. 61/449,046, filed on Mar. 3, 2011 and titled“III-Nitride Material Interlayer Structures”, and may further includeother transition layers reported in U.S. Pat. No. 6,617,060, issued onSep. 9, 2003 and titled “Gallium Nitride Materials And Methods”; U.S.Pat. No. 6,649,287, issued on Nov. 18, 2003 and titled “Gallium NitrideMaterials And Methods”; U.S. patent application Ser. No. 12/587,964,filed on Oct. 14, 2009 and titled “Group III-V Semiconductor Device withStrain-relieving Interlayers”; and U.S. patent application Ser. No.12/928,946, filed on Dec. 21, 2010 and titled “Stress Modulated GroupIII-V Semiconductor Device and Related Method”, the entire disclosuresof which are hereby incorporated fully by reference into the presentapplication.

In addition, or alternatively, transition body 210 may include aIII-Nitride or other group III-V transition structure. For example,transition body 210 may include a III-Nitride superlattice structure orstructures as disclosed in U.S. Pat. No. 6,649,287 issued on Nov. 18,2003 and titled “Gallium Nitride Materials And Methods”; U.S. Pat. No.7,112,830 issued on Sep. 26, 2006 and titled “Super Lattice ModificationOf Overlying Transistor”; U.S. Pat. No. 7,456,442 issued on Nov. 25,2008 and titled “Super Lattice Modification Of Overlying Transistor”;and U.S. patent application Ser. No. 11/531,508 filed on Sep. 13, 2006and titled “Process for Manufacture of Super Lattice Using AlternatingHigh and Low Temperature Layers to Block Parasitic Current Path”, theentire disclosures of which are hereby incorporated fully by referenceinto the present application.

In some implementations, transition body 210 includes a III-Nitride orother group 111-V transition structure having a selectively modifiedimpurity concentration such that a bottom surface impurity concentrationof the group III-V transition structure is selectively modified to a topsurface impurity concentration of the group III-V transition structure.For example, in one implementation, the impurity concentration oftransition body 210 may be selectively modified between bottom surface209 of transition body 210 and a top surface of transition body 210underlying bottom surface 211 of III-Nitride intermediate body 212. Sucha selective modification of the impurity concentration in transitionbody 210 may be performed utilizing a number of different impurityconcentration profiles or dopant grading schemes. For example, theimpurity concentration may be selectively modified continuously, in astep-wise manner, or may rise and fall between the bottom surfaceimpurity concentration and the top surface impurity concentration. Inaddition, the impurity concentration may be selectively modified acrossthe entire thickness of transition body 210, or across only a portion oftransition body 210.

Referring to III-Nitride intermediate body 212, in some implementations,III-Nitride intermediate body 212 may be a binary constant compositionsuch as AlN, GaN, or indium nitride (InN), for example. However, inother implementations, it may be preferable that the III-Nitrideintermediate body 212 be composed of an alloy of a Iii-Nitride materialsuch as Al_(x)In_(y)Ga_((1-x-y))N, Al_(x)Ga_((1-x))N, andIn_(y)Ga_((1-y))N. It is noted, moreover, that III-Nitride materialshaving other compositions may also be used.

As further shown in FIG. 2, III-Nitride intermediate body 212 havingbottom surface 211 is fabricated over transition body 210. III-Nitrideintermediate body 212 may be of constant alloy composition, or incertain other implementations, may be compositionally graded betweenbottom surface 211 and top surface 213. In one implementation, forexample, the alloy composition of III-Nitride intermediate body 212 maybe continuously graded between bottom surface 211 and top surface 213.III-Nitride device layer 214 may then be fabricated over top surface 213of III-Nitride intermediate body 212.

When semiconductor structure 200 forms a HEMT, it may be advantageous tofabricate III-Nitride device layer 214 to include a GaN channel layer(GaN channel layer not shown as such in FIG. 2) having a low impurityconcentration so as to minimize trapping centers and enhance 2DEGformation within III-Nitride device layer 214. However, in certain otherimplementations, it may be preferable that III-Nitride device layer 214be intentionally doped wither either N type or P type dopants, dependingon the device design and intended application. In substantially allcases, reducing the impurity concentration, for example, the carbonimpurity concentration, within III-Nitride device layer 214 as well asreducing the impurity concentration across at least a portion ofIII-Nitride intermediate body 212 is desirable.

For example, it may be advantageous or desirable to continuously reducethe impurity concentration between bottom surface 211 and top surface213 of III-Nitride intermediate body 212 in a manner consistent with thepenetration depth of critical electric fields produced by application ofa drain bias voltage to a device fabricated in III-Nitride device layer214. It is noted that, as used herein, critical electric field isdefined as the minimum field, associated with an applied voltage on thedrain, which results in a high probability of changing the charge stateof an impurity residing within the critical electric field perimeterwithin a III-Nitride layer(s). The critical electric field isproportional to the maximum applied drain bias voltages during operationof the device. As a result, in certain implementations, it may bedesirable for III-Nitride intermediate body 212 to have a higherimpurity concentration at bottom surface 211 and a lower impurityconcentration at top surface 213. It may also be advantageous to havethe lower impurity concentration at top surface 213 be maintained at asubstantially constant low level into III-Nitride device layer 214.

The impurity concentration in III-Nitride intermediate body 212 may bereduced between bottom surface 211 and top surface 213 utilizing anumber of different impurity concentration profiles or dopant gradingschemes. For example, the impurity concentration may be reducedcontinuously, in a step-wise manner, or may rise and fall between thehigher impurity concentration and the lower impurity concentration, forexample. In addition, the impurity concentration may be reduced acrossthe entire thickness of III-Nitride intermediate body 212, or acrossonly a portion of the thickness.

FIGS. 3, 4, 5A through 5H, 6A through 6D, and 7A through 7F (hereinafter“FIGS. 3-7F”) illustrate exemplary impurity concentration profiles forwhich the impurity concentration is selectively reduced as a function ofthickness across III-Nitride intermediate body 212 or semiconductorstructure 200. The selective reduction in impurity concentrationrepresented by FIGS. 3-7F may be seen to correspond to the selectivereduction in carbon concentration across the thickness of III-Nitrideintermediate body 212 or semiconductor structure 200, in FIG. 2.However, it is to be understood that in other implementations the graphsshown in any or all of FIGS. 3-7F may represent the concentration ofother impurities or dopants (e.g., H, O). The convention used in thepresent figures is that the thickness of III-Nitride intermediate body212 or semiconductor structure 200, in FIG. 2, increases in thedirection away from bottom surface 211 of III-Nitride intermediate body212 and towards top surface 215 of III-Nitride device layer 214.

The impurity concentration profiles represented in FIGS. 3-7F cancorrespond in general to the growth rate and/or growth temperature ofIII-Nitride intermediate body 212, as noted above. For example,fabricating III-Nitride intermediate body 212 so as to selectivelyreduce its impurity concentration from a higher impurity concentrationat bottom surface 211 to a lower impurity concentration at top surface213 may correspond to selectively reducing the growth rate ofIII-Nitride intermediate body 212 from a higher growth rate at bottomsurface 211 to a lower growth rate at top surface 213. Conversely,fabricating III-Nitride intermediate body 212 so as to selectivelyreduce its impurity concentration from a higher impurity concentrationat bottom surface 211 to a lower impurity concentration at top surface213 may correspond to selectively increasing the growth temperature ofIII-Nitride intermediate body 212 from a lower growth temperature atbottom surface 211 to a higher growth temperature at top surface 213.

As a specific example of the latter implementation, the growthtemperature at bottom surface 211 of III-Nitride intermediate body 212may be approximately 930° C. and may remain substantially unchangedduring the first approximately 1 micrometer (1 um) of growth.Thereafter, the growth temperature may be increased by approximately 20°C. to approximately 40° C. for each approximately 1 um of growth, up toa higher temperature in a range from approximately 1000° C. toapproximately 1020° C. at top surface 213. Such an increase intemperature may be continuous or step-wise, for example.

Referring to FIG. 3, FIG. 3 presents graph 300 corresponding to acontinuously reduced impurity concentration across III-Nitrideintermediate body 212, in FIG. 2, according to an exemplaryimplementation. Graph 300 includes impurity concentration profile 320showing a continuous reduction of impurity concentration at asubstantially constant rate from bottom surface 211 to top surface 213of III-Nitride intermediate body 212.

Moving to FIG. 4, FIG. 4 presents graph 400 corresponding to anotherexemplary implementation of a reduced impurity concentration acrossIII-Nitride intermediate body 212. Graph 400 includes impurityconcentration profile 420 showing a continuous reduction of impurityconcentration at a substantially constant rate from bottom surface 211to a depth within III-Nitride intermediate body 212 denoted as “d”. Thecontinuously reduced impurity concentration shown by impurityconcentration profile 420 then maintains a substantially constant valueat an impurity concentration lower than the impurity concentration atbottom surface 211 between depth “d” and top surface 213 of III-Nitrideintermediate body 212.

FIG. 5A presents graph 500A corresponding to another exemplaryimplementation of a continuously reduced impurity concentration acrossIII-Nitride intermediate body 212. Graph 500A includes impurityconcentration profile 520A showing an initial substantially constantimpurity concentration from bottom surface 211 to first intermediatedepth “a”, and then a continuous reduction of the impurity concentrationat a substantially constant rate as a function of position from depth“a” to depth “b” within III-Nitride intermediate body 212. Thecontinuously reduced impurity concentration shown by impurityconcentration profile 520A then maintains a substantially constant valueat an impurity concentration lower than the impurity concentration atbottom surface 211 between depth “b” and top surface 213 of III-Nitrideintermediate body 212.

FIG. 5B presents graph 500B corresponding to another exemplaryimplementation of a reduced impurity concentration across III-Nitrideintermediate body 212. Graph 500B includes impurity concentrationprofile 520B showing a selective step-wise reduction of impurityconcentration which includes two steps. Moreover, FIG. 5C presents graph500C showing impurity concentration profile 520C of a step-wisereduction of impurity concentration as a function of thickness includingmultiple steps.

FIGS. 5D, 5E, and 5F show respective graphs 500D, 500E, and 500F ofimpurity concentration profiles 520D, 520E, and 520F, respectively,depicting selectively reduced impurity concentrations that arecontinuously reduced at various exponential rates from a higher impurityconcentration to a lower impurity concentration. It is noted that thehigher impurity concentration is substantially equal to the impurityconcentration at bottom surface 211 of III-Nitride intermediate body212, while the lower impurity concentration is substantially equal tothe impurity concentration at top surface 213 of III-Nitrideintermediate body 212.

FIG. 5G presents graph 500G corresponding to another exemplaryimplementation of a selectively reduced impurity concentration acrossIII-Nitride intermediate body 212. Graph 500G includes impurityconcentration profile 520G showing that the impurity concentration mayrise and fall between the higher impurity concentration at bottomsurface 211 and the lower impurity concentration at top surface 213. Inaddition, FIG. 5H presents graph 500H showing impurity concentrationprofile 520H of a step-wise reduction of impurity concentrationincluding continuous and substantially constant reductions in impurityconcentration between adjacent steps.

In some implementations, III-Nitride intermediate body 212 may be animpurity graded superlattice, or an impurity graded or compositionallygraded superlattice. That is to say, III-Nitride intermediate body 212may include two or more alternating sub-layers of III-Nitride materialshaving different III-Nitride compositions. Moreover, the two or morealternating sub-layers may have different impurity concentrations, ordifferent selectively reduced impurity concentration profiles. Fourexemplary superlattice implementations are shown in FIGS. 6A through 6D.

Referring to FIG. 6A, FIG. 6A presents graph 600A corresponding toanother exemplary implementation of a selectively reduced impurityconcentration across III-Nitride intermediate body 212. Graph 600Aincludes impurity concentration profile 620A showing an exemplaryimpurity concentration profile resulting from alternating sub-layerswhen III-Nitride intermediate body 212 is fabricated as a superlattice.According to the implementation shown in FIG. 6A, each alternatingsub-layer of the superlattice has a different but substantially constantimpurity concentration level throughout the sub-layer. A stepwise changein impurity concentration occurs at the sub-layer interfaces and resultsin a reduced impurity concentration from bottom surface 211 to topsurface 213.

Moving to FIG. 6B, FIG. 6B presents graph 600B corresponding to anotherexemplary implementation of a selectively reduced impurity concentrationacross III-Nitride intermediate body 212. Graph 600B includes impurityconcentration profile 620B showing another exemplary impurityconcentration profile resulting from alternating sub-layers whenIII-Nitride intermediate body 212 is fabricated as a superlattice.According to the implementation shown in FIG. 6B, one of the sub-layerimpurity concentrations is held substantially constant across thesuperlattice layer at the lower impurity concentration. The othersub-layer has a graded impurity concentration which continuouslydecreases at a substantially constant rate across the superlatticesub-layer.

In FIG. 6C, impurity concentration profile 620C of graph 600C also showsthat one of the sub-layer impurity concentrations is held substantiallyconstant across each iteration of the sub-layer within the superlatticeat the lower impurity concentration. However, according to the exemplaryimplementation of FIG. 6C, the intervening sub-layers have respectiveimpurity concentrations that decrease in a stepwise fashion across thesuperlattice, while remaining substantially constant within eachsub-layer of the superlattice. Alternatively, impurity concentrationprofile 620D of graph 600D, in FIG. 6D, shows both alternating sets ofsub-layers within the superlattice having impurity concentrationprofiles that decrease stepwise across the superlattice, while remainingsubstantially constant within each sub-layer of the superlattice.

It is reiterated that the impurity concentration profiles of III-Nitrideintermediate body 212 illustrated in FIGS. 3 through 6D are merelyexemplary. In other implementations, the impurity concentration ofIII-Nitride body 212 may be selectively reduced according to otherprofiles that are within the scope of the present inventive concepts.Moreover, in addition to selectively reducing the impurity concentrationacross III-Nitride intermediate body 212 from bottom surface 211 to topsurface 213, the present concepts also include tailoring the impurityconcentration profile across other portions of semiconductor structure200, as shown in FIGS. 7A through 7F.

FIG. 7A presents graph 700A corresponding to a selectively reducedimpurity concentration, showing a continuous reduction in impurityconcentration across portions of semiconductor structure 200, in FIG. 2,according to one exemplary implementation. Graph 700A includes impurityconcentration profile 720A showing a continuous and substantiallyconstant reduction in impurity concentration across transition body 210from bottom surface 209 of transition body 210 to bottom surface 211 ofIII-Nitride intermediate body 212. Impurity concentration profile 720Athen shows a stepped reduction in impurity concentration at bottomsurface 211 of III-Nitride intermediate body 212, followed by acontinuous and substantially constant reduction in impurityconcentration across III-Nitride intermediate body 212 to top surface213 of III-Nitride intermediate body 212. It is noted that therespective substantially constant rates of reduction across transitionbody 210 and III-Nitride intermediate body 212 may be different rates ofreduction, as shown in FIG. 7A, or they may be substantially the samerate of reduction. Impurity concentration profile 720A then continueswith another stepped reduction in impurity concentration at top surface213 of III-Nitride intermediate body 212, followed by a substantiallyconstant low level impurity concentration throughout III-Nitride devicelayer 214, to top surface 215.

Referring to FIG. 7B, FIG. 7B presents graph 700B corresponding to aselectively reduced impurity concentration, showing a continuousreduction in impurity concentration across portions of semiconductorstructure 200, according to another exemplary implementation. Graph 700Bincludes impurity concentration profile 720B showing a continuous andsubstantially constant reduction in impurity concentration at a firstrate of reduction across transition body 210 from bottom surface 209 oftransition body 210 to bottom surface 211 of III-Nitride intermediatebody 212. Impurity concentration profile 720B then shows a steppedreduction in impurity concentration at bottom surface 211 of III-Nitrideintermediate body 212, followed by a continuous and substantiallyconstant reduction in impurity concentration at a second rate ofreduction, from bottom surface 211 to depth “d” in III-Nitrideintermediate body 212. Impurity concentration profile 720B then shows asubstantially constant low level impurity concentration from depth “d”through top surface 213 of III-Nitride intermediate body 212, to topsurface 215 of III-Nitride device layer 214.

Moving to FIG. 7C, FIG. 7C presents graph 700C corresponding to aselectively reduced impurity concentration, showing a continuousreduction in impurity concentration across portions of semiconductorstructure 200, according to still another exemplary implementation.Graph 700C includes impurity concentration profile 720C showing acontinuous and substantially constant high impurity concentration acrosstransition body 210 and across bottom surface 211 of III-Nitrideintermediate body 212 to depth “a” in III-Nitride intermediate body 212.Impurity concentration profile 720C then shows a continuous andsubstantially constant reduction in impurity concentration from depth“a” to depth “d” in III-Nitride intermediate body 212. Impurityconcentration profile 720C further shows a substantially constant lowlevel impurity concentration from depth “d” through top surface 213 ofIII-Nitride intermediate body 212, to top surface 215 of III-Nitridedevice layer 214.

Referring to FIG. 7D, FIG. 7D presents graph 700D corresponding to aselectively reduced impurity concentration, showing a continuousreduction in impurity concentration across portions of semiconductorstructure 200, according to another exemplary implementation. Graph 700Dincludes impurity concentration profile 720D showing a continuous andsubstantially constant reduction in impurity concentration at a firstrate of reduction across transition body 210 from bottom surface 209 oftransition body 210 to bottom surface 211 of III-Nitride intermediatebody 212. Impurity concentration profile 720D then shows a steppedreduction in impurity concentration at bottom surface 211 of III-Nitrideintermediate body 212, followed by a continuous and substantiallyconstant reduction in impurity concentration at a second rate ofreduction, from bottom surface 211 to depth “a” in III-Nitrideintermediate body 212. Impurity concentration profile 720D also shows acontinuous and substantially constant reduction in impurityconcentration at a third rate of reduction from depth “a” to depth “d”in III-Nitride intermediate body 212. Impurity concentration profile720D then shows a substantially constant low level impurityconcentration from depth “d” through top surface 213 of III-Nitrideintermediate body 212, to top surface 215 of III-Nitride device layer214.

FIG. 7E presents graph 700E corresponding to a selectively modifiedimpurity concentration across portions of transition body 210 ofsemiconductor structure 200, and a continuous reduction in impurityconcentration across a portion of III-Nitride intermediate body 212,according to one exemplary implementation. Graph 700E includes impurityconcentration profile 720E showing a selectively modified impurityconcentration across transition body 210, followed by a continuous andsubstantially constant reduction in impurity concentration withinIII-Nitride intermediate body 212, followed in turn by a substantiallyconstant low level impurity concentration across III-Nitride devicelayer 214.

FIG. 7F presents graph 700F corresponding to a selectively modifiedimpurity concentration across portions of transition body 210 ofsemiconductor structure 200, and a continuous reduction in impurityconcentration across a portion of III-Nitride intermediate body 212,according to another exemplary implementation. Graph 700F includesimpurity concentration profile 720F showing a selectively modifiedimpurity concentration across transition body 210. Impurityconcentration profile 720F shows a selectively modified impurityconcentration from a bottom surface impurity concentration at bottomsurface 209 of transition body 210 to a top surface impurityconcentration substantially matching the impurity concentration atbottom surface 211 of III-Nitride intermediate body 212. Impurityconcentration profile 720F is then continuously reduced at a first rateof reduction across III-Nitride intermediate body 212 to depth “a” inIII-Nitride intermediate body 212. Impurity concentration profile 720Falso shows a continuous and substantially constant reduction in impurityconcentration at a second rate of reduction from depth “a” to depth “d”in III-Nitride intermediate body 212. Impurity concentration profile720F then shows a substantially constant low level impurityconcentration from depth “d” through top surface 213 of III-Nitrideintermediate body 212, to top surface 215 of III-Nitride device layer214.

The impurity concentration profile across transition body 210 may bestep-wise and may rise and fall, as shown in FIGS. 7E and 7F, and/or maycorrespond to a transition layer scheme, including additionalinterlayers each having a different respective impurity concentration,as described in U.S. Provisional Patent Application No. 61/449,046,flied on Mar. 3, 2011 and titled “III-Nitride Material InterlayerStructures,” the entire disclosure of which is hereby incorporated fullyby reference into the present application. The impurities or dopantsgiving rise to the impurity concentration profile of transition body 210may be unintentionally present or may be intentionally added duringfabrication of transition body 210.

III-Nitride device layer 214 of semiconductor structure 200, in FIG. 2,may include a FET or a HEMT, for example. In implementations in whichsemiconductor structure 200 forms a HEMT, III-Nitride device layer 214may be seen to represent any or all of several layers including, forexample, a GaN channel layer, an AlN spacer layer, an AlGaN barrierlayer and other layers including passivation, metal, and P typeIII-Nitride gate layers needed for device formation.

In implementations in which III-Nitride device layer 214 corresponds toa GaN channel layer of a HEMT device, it may be desirable for theimpurity concentration, and in particular for the concentration of Ptype impurities, to be substantially minimized. For example, anundesirably high P type or other impurity concentration may interferewith electron mobility and 2DEG formation, and in some instances mayresult in increased dynamic Rdson, increased leakage, and lower standoffor breakdown voltages. In practice, the thickness of the GaN channellayer may be relatively thin. That is to say, the GaN channel layer maybe no thicker than necessary to support heterojunction formation suchthat a conductive 2DEG channel forms near the heterojunction interface.

In some implementations, III-Nitride device layer 214 may be implementedas a GaN channel layer having a thickness in a range from approximately0.1 um to approximately 0.5 um. In other implementations, III-Nitridedevice layer 214 may be implemented as a GaN channel layer having athickness in a range from approximately 0.15 um to approximately 0.25um. Several HEMT structures formed of various III-Nitride device layerscorresponding to III-Nitride device layer 214 are described in U.S. Pat.No. 6,849,882, issued on Feb. 1, 2005 and titled “Group-III NitrideBased High Electron Mobility Transistor (HEMT) with Barrier/SpacerLayer”; U.S. Pat. No. 7,382,001, issued on Jun. 3, 2008 and titled“Enhancement Mode III-Nitride FET”; U.S. Pat. No. 7,759,699, issued onJul. 20, 2010 and titled “III-Nitride Enhancement Mode Devices”; U.S.Pat. No. 5,192,987, issued on Mar. 9, 1993 and titled “High ElectronMobility Transistor with GAN/ALXGAl-XN Heterojunctions”; and U.S. Pat.No. 7,745,849, issued on Jun. 29, 2010 and titled “Enhancement ModeIII-Nitride Semiconductor Device with Reduced Electric Field Between theGate and the Drain”; as well as U.S. patent application Ser. No.13/021,437, filed on Feb. 4, 2011 and titled “Programmable III-NitrideTransistor with Aluminum-Doped Gate”; U.S. patent application Ser. No.13/017,970, filed on Jan. 31, 2011 and titled “Enhancement ModeIII-Nitride Transistors with Single Gate Dielectric Structure”; U.S.patent application Ser. No. 12/653,097, filed on Dec. 7, 2009 and titled“Gated AlGaN/GaN Heterojunction Schottky Device”; U.S. patentapplication Ser. No. 12/195,801, filed on Aug. 21, 2008 and titled“Enhancement Mode III-Nitride Device with Floating Gate and Process forIts Manufacture”; U.S. patent application Ser. No. 12/211,120, filed onSep. 16, 2008 and titled “III-Nitride Semiconductor Device with ReducedElectric Field Between Gate and Drain and Process for Its Manufacture”;and U.S. patent application Ser. No. 11/857,113, filed on Sep. 18, 2007and titled “III-Nitride Power Semiconductor Device Having a ProgrammableGate”, the entire disclosures of which are hereby incorporated fully byreference into the present application.

Is some implementations, semiconductor structure 200 may form a highvoltage FET or HEMT. In such implementations, the device geometriesand/or III-Nitride material layer thicknesses may need to be altered toaccommodate the high voltage and resulting critical high voltageelectric fields. For example, as the applied voltage is increased for agiven device, the electric field associated with the drain electrodewill also increase in both the lateral direction and the penetrationdepth into the device structure. At higher applied voltages in a HEMTstructure, the penetration depth of the electric field may extend underthe drain region to a depth greater than the 2DEG, and perhaps greaterthan the thickness of III-Nitride device layer 214, thereby extendinginto III-Nitride intermediate body 212. Under such conditions, anyimpurities within the channel region of III-Nitride device layer 214, oreven within some regions of III-Nitride intermediate body 212, may actas trapping centers and may subsequently change the charge state withinthe effected layers, resulting in degradation of high voltage HEMTperformance. As a result, it may be desirable to reduce or substantiallyminimize the impurity concentrations not only in the channel region ofIII-Nitride device layer 214, but also into III-Nitride intermediatebody 212.

By contrast, it may be advantageous to have a relatively high impurityconcentration, such as a high carbon concentration, below III-Nitridedevice layer 214 in order to improve the resistivity of III-Nitrideintermediate body 212 and thereby improve standoff voltage capability.The result is a conflicting set of design objectives, driven by the needfor a high impurity concentration (e.g., carbon concentration) inIII-Nitride intermediate body 212 to enhance breakdown resistance, andconcurrently a low impurity concentration (e.g., carbon concentration)in III-Nitride intermediate body 212 to minimize trapping and to reducedynamic Rdson. That conflict may be resolved by implementing III-Nitrideintermediate body 212 having a selectively reduced impurityconcentration, wherein a higher impurity concentration at bottom surface211 is selectively reduced to a lower impurity concentration at topsurface 213, as disclosed herein.

Referring now to FIG. 8, a III-Nitride material stack is shown whichforms a typical GaN based HEMT structure 800. Structure 800 includestransition body 210. As noted above, transition body 210 may be formedas a III-Nitride transition body including AlN, for example. Transitionbody 210 may be fabricated over a III-Nitride nucleation, strainrelieving layer(s), other additional layer(s), as well as a substratecorresponding to substrate 202, in FIG. 2 (substrate and any layersunderlying transition body 210 not shown in FIG. 8).

Structure 800 also included III-Nitride intermediate body 212 havingbottom surface 211 fabricated over transition body 210. In someimplementations, it may be preferred that III-Nitride intermediate body212 be fabricated as a constant alloy composition of Al_(x)Ga_(1-x)Nwhere 0.04<x<0.10. It may also be advantageous that a thickness ofIII-Nitride intermediate body 212, that is the distance from bottomsurface 211 to top surface 213 across III-Nitride intermediate body 212,be in a range from approximately 200 nm to approximately 2,000 nm.

As further shown in FIG. 8, III-Nitride device layer 214 is fabricatedover layer III-Nitride intermediate body 212. III-Nitride device layer214 represents the III-Nitride HEMT device layers and may includeseveral sub-layers including GaN based channel layer 214 a, AlGaNbarrier layer and spacer layers 214 b, and dielectric layer or otherlayers 214 c. Although three exemplary sub-layers are shown in FIG. 8,other layers or sub-layers may also be included and are within the scopeof the present inventive concepts. Also shown in FIG. 8 is 2DEG 216 anddrain contact or electrode 218. It is noted that source and gatecontacts or electrodes are omitted from FIG. 8 for conceptual clarity.

If properly constructed, structure 800 will generate 2DEG 216 near theinterface of GaN channel layer 214 a and the AlGaN barrier layerincluded in AlGaN device layers 214 b. According to the implementationshown in FIG. 8, structure 800 provides a depletion mode (normally ON)HEMT, and 2DEG 216 would exist in a state when there is no applied gatevoltage. 2DEG 216 includes high mobility electrons which are themajority carriers traveling from the source (not shown) to drain contactor electrode 218 of structure 800.

During operation of the HEMT, when a voltage bias is applied to draincontact or electrode 218 of structure 800, a critical electric fieldwill be generated under drain contact or electrode 218 that isproportional to the voltage applied to drain contact or electrode 218.It is reiterated that, as used herein, critical electric field isdefined as the minimum field, associated with an applied voltage todrain contact or electrode 218, which results in a high probability ofchanging the charge state of an impurity residing within the criticalelectric field perimeter of an effected III-Nitride layer(s).

As an example, for a given voltage 1 (V1) applied to drain contact orelectrode 218, the corresponding critical electric field is shown inFIG. 8 as E_(CRITICAL1). E_(CRITICAL1) will penetrate into GaN channellayer 214 a and may also extend into III-Nitride intermediate body 212to a depth denoted as d1 in FIG. 8. Any impurities or trapping centerswhich fall within the penetration depth of E_(CRITICAL1) have anincreased probability of having their charge states altered.

As the applied voltage is increased to a higher voltage 2 (V2), thecritical electric field E_(CRITICAL2) will influence the charge state ofthe impurities deeper into III-Nitride intermediate body 212 to depthd2. As a result, the probability of changing the charge state willincrease within that extended field effected area. At high voltageoperation, the critical electric field denoted as E_(CRITICAL3) willinfluence the charge states even deeper into the III-Nitrideintermediate body 212 to depth d3, and the probability of changingcharge states is increased still further.

If there are any P type impurities, e.g., carbon impurities, locatedwithin aN channel layer 214 a and III-Nitride intermediate body 212,there is a high probability that their charge states will change if theyfall within a region subject to the critical electric fields. Thesechanged charge state impurities, or traps, can adversely impact theswitching speed and dynamic Rdson of the HEMT formed by structure 800.Consequently, it is desirable to minimize impurities or acceptor stateswithin GaN channel layer 214 a, as well as in III-Nitride intermediatebody 212 within the regions subject to the critical electric fieldsformed during operation of the device. Therefore, depending on thepenetration depth of the critical electric fields, it would be desirableto reduce or substantially minimize impurity concentrations within GaNchannel layer 214 a and also within at least a portion of III-Nitrideintermediate body 212.

However, as discussed above, there is the conflicting objective offabricating III-Nitride intermediate body 212 to have a highconcentration of carbon impurities near bottom surface 211 and intounderlying transition body 210 to improve the resistivity and enhancethe standoff voltage capability of the HEMT formed by structure 800.FIG. 8 shows three examples of solutions for resolving the apparentconflict by selectively reducing the impurity concentration from ahigher impurity concentration at bottom surface 211 of III-Nitrideintermediate body 212 to a lower impurity concentration at top surface213 of III-Nitride intermediate body 212.

For example, if structure 800 is designed for a low voltage application(e.g., V1) then under an applied voltage to drain contact or electrode218, a corresponding critical electric field E_(CRITICAL1) will developin proximity to the drain region and penetrate to a depth of d1 withinIII-Nitride intermediate layer 212. Consequently, it would be desirableto form III-Nitride intermediate layer 212 such that the carbon impurityconcentration starts at a higher level upon initiation of growth (i.e.,at bottom surface 211), followed by a continuous decrease at a constantrate to a lower level at a depth of at least d1. It would then furtherbe desirable to maintain the impurity concentration at or near the lowerlevel throughout the remainder of the growth of III-Nitride intermediatebody 212 (i.e., to top surface 213). By selectively reducing the carbonimpurity concentration to a lower (i.e., substantially minimal)concentration at a depth of d1, the present solution reduces orsubstantially minimized the population of carbon impurities with thehighest probability of having their charge states changed under biasingof the device at voltage (V1).

Alternatively, if structure 800 is designed to operate at a higher drainvoltage of V2, then it would be desirable to minimize the carbonimpurity concentration within the area influenced by the subsequentcritical electric field, E_(CRITICAL2) to depth d2 within III-Nitrideintermediate body 212. According to this implementation, an impurityconcentration profile analogous to that formed in response toE_(CRITICAL1) can be formed in III-Nitride intermediate body 212.However, the rate of reduction of the impurity concentration can beincreased such that a lower (i.e., substantially minimal) impurityconcentration is reached at depth of d2, as shown in FIG. 8.

Moreover, if structure 800 is designed to operate at a yet higher drainvoltage of V3, it would be desirable to minimize the carbon impurityconcentration within the area influenced by the subsequent criticalelectric field E_(CRITICAL3) to an even deeper depth within III-Nitrideintermediate layer 212, denoted as d3. Once again, an impurityconcentration profile analogous to that formed in response toE_(CRITICAL1) can be formed in III-Nitride intermediate body 212.However, the rate of reduction of the impurity concentration can beincreased still more such that a lower (i.e., substantially minimal)impurity concentration is reached at depth of d3, as shown in FIG. 8.

Thus, implementations of the present inventive concepts provide a groupIII-V device structure having a selectively reduced impurityconcentration. By fabricating a group III-V device layer over a groupIII-V intermediate body having a selectively reduced impurityconcentration, improved device performance and reliability may beachieved. For example, by continuously reducing the impurityconcentration from a higher impurity concentration at a bottom surfaceof the group III-V intermediate body to a lower impurity concentrationat a top surface of the group III-V intermediate body, the presentsolution enables reduced leakage and enhanced standoff voltagecapability while concurrently enabling high speed switching by reducingor substantially minimizing sources of undesirable dynamic Rdson.

From the above description it is manifest that various techniques can beused for implementing the concepts described in the present applicationwithout departing from the scope of those concepts. Moreover, while theconcepts have been described with specific reference to certainimplementations, a person of ordinary skill in the art would recognizethat changes can be made in form and detail without departing from thescope of those concepts. As such, the described implementations are tobe considered in all respects as illustrative and not restrictive. Itshould also be understood that the present application is not limited tothe particular implementations described herein, but manyrearrangements, modifications, and substitutions are possible withoutdeparting from the scope of the present disclosure.

1. A semiconductor structure comprising: a substrate; a transition bodyover said substrate; a group III-V intermediate body having a bottomsurface over said transition body; a group III-V device layer over a topsurface of said group III-V intermediate body; said group III-Vintermediate body having a continuously reduced impurity concentrationwherein a higher impurity concentration at said bottom surface iscontinuously reduced to a lower impurity concentration at said topsurface.
 2. The semiconductor structure of claim 1, wherein an impurityproducing said higher and lower impurity concentrations is a P typeimpurity.
 3. The semiconductor structure of claim 1, wherein saidcontinuously reduced impurity concentration comprises a continuouslyreduced carbon concentration.
 4. The semiconductor structure of claim 1,wherein said continuously reduced impurity concentration includes aplurality of impurity species.
 5. The semiconductor structure of claim1, wherein said group III-V intermediate body comprises acompositionally graded III-Nitride body having a first III-Nitridecomposition at said bottom surface and a second III-Nitride compositionabove said bottom surface.
 6. The semiconductor structure of claim 1,wherein said group III-V device layer includes at least one of aIII-Nitride field-effect transistor (FET) and a III-Nitride highelectron mobility transistor (HEMT).
 7. The semiconductor structure ofclaim 1, wherein said transition body includes a group III-V transitionstructure having a selectively modified impurity concentration such thata bottom surface impurity concentration of said group III-V transitionstructure is selectively modified to a top surface impurityconcentration of said group III-V transition structure.
 8. Thesemiconductor structure of claim 7, wherein said selectively modifiedimpurity concentration is modified in a step-wise fashion from saidbottom surface impurity concentration to said top surface impurityconcentration.
 9. The semiconductor structure of claim 7, wherein saidselectively modified impurity concentration rises and falls between saidbottom surface impurity concentration and said top surface impurityconcentration.
 10. A method comprising: fabricating a transition bodyover a substrate; fabricating a group III-V intermediate body having abottom surface over said transition body; fabricating a group III-Vdevice layer over a top surface of said group III-V intermediate body;wherein fabricating said group III-V intermediate body comprises forminga continuously reduced impurity concentration such that a higherimpurity concentration at said bottom surface is continuously reduced toa lower impurity concentration at said top surface.
 11. The method ofclaim 10, wherein fabricating said group III-V intermediate bodycomprises selectively reducing a growth rate of said group III-Vintermediate body from a higher growth rate at said bottom surface to alower growth rate at said top surface.
 12. The method of claim 10,wherein fabricating said group III-V intermediate body comprisesselectively increasing a growth temperature of said group III-Vintermediate body from a lower growth temperature at said bottom surfaceto a higher growth temperature at said top surface.
 13. The method ofclaim 10, wherein an impurity producing said higher and lower impurityconcentrations is a P type impurity.
 14. The method of claim 10, whereinforming said continuously reduced impurity concentration comprisesforming a continuously reduced carbon concentration.
 15. The method ofclaim 10, wherein said continuously reduced impurity concentrationincludes a plurality of impurity species.
 16. The method of claim 10,wherein said group III-V intermediate body comprises a compositionallygraded III-Nitride body having a first III-Nitride composition at saidbottom surface and a second III-Nitride composition above said bottomsurface.
 17. The method of claim 10, wherein said group III-V devicelayer includes at least one of a III-Nitride field-effect transistor(FET) and a III-Nitride high electron mobility transistor (HEMT). 18.The method of claim 10, wherein fabricating said transition bodyincludes fabricating a group III-V transition structure having aselectively modified impurity concentration such that a bottom surfaceimpurity concentration of said group III-V transition structure isselectively modified to a top surface impurity concentration of saidgroup III-V transition structure.
 19. The method of claim 18, whereinsaid selectively modified impurity concentration is reduced in astep-wise fashion from said bottom surface impurity concentration tosaid top surface impurity concentration.
 20. The method of claim 18,wherein said selectively modified impurity concentration rises and fallsbetween said bottom surface impurity concentration and said top surfaceimpurity concentration.